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Journal of Sciences Islamic Republic of Iran، جلد ۲۳، شماره ۱، صفحات ۲۹-۳۶
عنوان فارسی Immobilization of Cu(II)-Histidine Complex on Al-MCM-۴۱ as Catalyst for Epoxidation of Alkenes
چکیده فارسی مقاله Cu(II) complex with L-histidine (His) ligand, immobilized within Al-MCM-41, designated as Cu(His)2/Al-MCM-41 was prepared and characterized by powder X-ray diffraction (XRD), nitrogen adsorption desorption, FTIR, UV-Vis and chemical analysis techniques. The surface area and pore volume were found to decrease after immobilization of Cu(II) complex on Al-MCM-41. It was found that Cu(His)2/Al-MCM-41 catalyze the oxidation of some alkenes such as norbornene and trans-stilbene with tert-butylhydroperoxide (TBHP) with high activity and selectivity to the corresponding epoxides. It was concluded that the Al-MCM-41 nanoreactors is a suitable support for immobilization of biomimetic molecules. Particularly significant is that no desorption was observed during the course of reactions.
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عنوان انگلیسی Immobilization of Cu(II)-Histidine Complex on Al-MCM-41 as Catalyst for Epoxidation of Alkenes
چکیده انگلیسی مقاله Cu(II) complex with L-histidine (His) ligand, immobilized within Al-MCM-41, designated as Cu(His)2/Al-MCM-41 was prepared and characterized by powder X-ray diffraction (XRD), nitrogen adsorption desorption, FTIR, UV-Vis and chemical analysis techniques. The surface area and pore volume were found to decrease after immobilization of Cu(II) complex on Al-MCM-41. It was found that Cu(His)2/Al-MCM-41 catalyze the oxidation of some alkenes such as norbornene and trans-stilbene with tert-butylhydroperoxide (TBHP) with high activity and selectivity to the corresponding epoxides. It was concluded that the Al-MCM-41 nanoreactors is a suitable support for immobilization of biomimetic molecules. Particularly significant is that no desorption was observed during the course of reactions.
کلیدواژه‌های انگلیسی مقاله Al-MCM-41, Histidine, Copper complex, Epoxidation
نویسندگان مقاله f فرزانه |
university of alzahra
سازمان اصلی تایید شده: دانشگاه الزهرا (Alzahra university)

نشانی اینترنتی http://jsciences.ut.ac.ir/article_24567_489834434eeeea0a0977cf718efdd216.pdf
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