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JCR 2016
جستجوی مقالات
یکشنبه 23 آذر 1404
Iranian Journal of Chemistry and Chemical Engineering
، جلد ۴۰، شماره ۵، صفحات ۱۴۴۶-۱۴۵۶
عنوان فارسی
چکیده فارسی مقاله
کلیدواژههای فارسی مقاله
عنوان انگلیسی
Advancements of Electrochemical Removal of o-Methylphenol from Aqueous Using BDD Anode Compared to Pt One: Kinetics and Mechanism Determination
چکیده انگلیسی مقاله
The oxidation of 216 mg/L o-methylphenol was studied in an acidic aqueous solution using Boron-Doped Diamond (BDD) and platinum
(Pt) anodes. o-methylphenol was oxidized by
hydroxyl
radicals
generated
on
the
anode
used,
however,
there
was
a
significant
distinction
betwixt
the BDD and Pt anodes in the effectiveness and accomplishment of electrochemical degradation. o-methylphenol was rapidly mineralized at the BDD anode, but its degradation was much slower at the Pt anode with a Total Organic Carbon (TOC) removal of 98% and 65% for BDD and Pt anodes, respectively. Using BDD anode, 3-methylcatechol, methylhydroquinone, and maleic, fumaric, pyruvic, formic, glyoxylic, succinic, oxalic, and acetic acids were detected. But, there was a formation of dark-colored polymeric compounds and precipitates in the solutions electrolyzed by the Pt anode, which was not observed for the BDD cells.
کلیدواژههای انگلیسی مقاله
Electrochemical oxidation,o-methylphenol,BDD anode,Hydroxyl radical,Degradation
نویسندگان مقاله
Nisrine Khadhri |
Laboratory for the Application of Materials to the Environment, Water and Energy (LR21ES15), Faculty of Sciences of Gafsa, University of Gafsa, TUNISIA
Mongi Ben Mosbah |
Laboratory for the Application of Materials to the Environment, Water and Energy (LR21ES15), Faculty of Sciences of Gafsa, University of Gafsa, TUNISIA
Nejmeddine Rabaaoui |
Laboratory for the Application of Materials to the Environment, Water and Energy (LR21ES15), Faculty of Sciences of Gafsa, University of Gafsa, TUNISIA
Mohamed Amine Khadimallah |
Prince Sattam Bin Abdulaziz University, College of Engineering, Civil Engineering Department, BP 655, Al-Kharj, 11942, SAUDI ARABIA
Younes Moussaoui |
Organic Chemistry Laboratory (LR17ES08), Faculty of Sciences of Sfax, University of Sfax, TUNISIA
نشانی اینترنتی
https://ijcce.ac.ir/article_39880_aa72ba58a5de3db9b39ca90450bb9a08.pdf
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