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JCR 2016
جستجوی مقالات
یکشنبه 23 آذر 1404
Iranian Journal of Chemistry and Chemical Engineering
، جلد ۳۹، شماره ۵، صفحات ۱۶۹-۱۷۹
عنوان فارسی
چکیده فارسی مقاله
کلیدواژههای فارسی مقاله
عنوان انگلیسی
The Removal of Cadmium, Cobalt, and Nickel by Adsorption with Na-Y Zeolite
چکیده انگلیسی مقاله
The article aims to study the removal of heavy metal ions Cd
2+
, Co
2+,
and Ni
2+
from an aqueous solution using faujasite NaY. The adsorption studies were carried out in the single and binary component system. Sorption experiments were performed in batch at pH (5–6), adsorbent dosage (0.15 g), and initial concentration (0.1–10 mmol/L). The single-ion equilibrium adsorption data were fitted to three isotherm models: Langmuir, Freundlich, and Dubinin-Radushkevich. Results showed that the Langmuir isotherm fits sorption data better than the Freundlich equation. The maximum adsorption capacities (Q
max
) were 0.81, 0.85 and 0.92 mmol/g for Cd
2+
, Ni
2+
and Co
2+
ions, respectively. Besides, the study of the competitive sorption of ions in a binary system showed that faujasite NaY preferentially adsorbs cations in the following order: Co
2+
>Ni
2+
>Cd
2+
. The obtained R
L
(separation factor or Langmuir parameter) values were in the range of 0–1 indicating that Cd
2+
, Co
2+,
and Ni
2+
sorption were favorable. The obtained mean free energy value for adsorption of Co
2+
and Ni
2+
were in the range of 8–16 kJ/mol, indicating that ions were uptaken through an ion exchange process.
کلیدواژههای انگلیسی مقاله
Faujasite NaY,Competitive adsorption,heavy metals,Isotherm modeling
نویسندگان مقاله
Manel Araissi |
Material Environment and Energy Laboratory (UR14ES26), Faculty of Sciences of Gafsa, University of Gafsa, Gafsa, TUNISIA
Elimame Elaloui |
Material Environment and Energy Laboratory (UR14ES26), Faculty of Sciences of Gafsa, University of Gafsa, Gafsa, TUNISIA
Younes Moussaoui |
Organic Chemistry Laboratory (LR17ES08), Faculty of Sciences of Sfax, University of Sfax, TUNISIA
نشانی اینترنتی
https://ijcce.ac.ir/article_32096_54134f3815606ca20072784102c5a7fe.pdf
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