این سایت در حال حاضر پشتیبانی نمی شود و امکان دارد داده های نشریات بروز نباشند
Analytical and Bioanalytical Electrochemistry، جلد ۱۶، شماره ۲، صفحات ۱۶۳-۱۷۴
عنوان فارسی
چکیده فارسی مقاله
کلیدواژه‌های فارسی مقاله
عنوان انگلیسی Performance of Potassium Iodate as an Electrocatalyst for the Oxidation of Secondary Alcohols Utilizing a Platinum Electrode in a Biphasic Medium
چکیده انگلیسی مقاله Potassium iodate was employed as a mediator with concentrated sulfuric acid to electrochemically oxidize substituted secondary alcohols in a biphasic medium with platinum electrodes. Using potassium iodate as a mediator in a biphasic medium, ketones were successfully generated from secondary alcohols. 1-phenyl ethanol is electrochemically oxidized to acetophenone in a biphasic medium. With maximum selectivity and good yields, the several substituted alcohols were successfully converted to ketones. The Platinum electrode had much more electrochemical activity and electrochemical products, according to the HPLC study that followed. The product aromatic ketones were described using UV, FTIR, 1H-NMR, and 13C-NMR spectroscopy, and the percentage of product yield was calculated using HPLC. Many secondary alcohols could also be converted to the appropriate ketones at room temperature, with isolated yields ranging from 80 to 95%. During recycling, the product's purity remained intact. It appears that this concept can grow while remaining pollution-free as a result.
کلیدواژه‌های انگلیسی مقاله 1-Phenylethanol, Aromatic secondary alcohol, biphasic medium, Platinum electrode, Potassium iodate
نویسندگان مقاله Susila G. Savari |
Department of Chemistry, St. Joseph’s College (Autonomous), Affiliated to Bharathidasan University, Tiruchirappalli-620 002, Tamilnadu, India

S. Joseph Selvaraj |
Department of Chemistry, St. Joseph’s College (Autonomous), Affiliated to Bharathidasan University, Tiruchirappalli-620 002, Tamilnadu, India

نشانی اینترنتی https://www.abechem.com/article_711553_e5ec59295f4994c18d02b348628c1200.pdf
فایل مقاله فایلی برای مقاله ذخیره نشده است
کد مقاله (doi)
زبان مقاله منتشر شده en
موضوعات مقاله منتشر شده
نوع مقاله منتشر شده
برگشت به: صفحه اول پایگاه   |   نسخه مرتبط   |   نشریه مرتبط   |   فهرست نشریات