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Iranian Journal of Chemistry and Chemical Engineering، جلد ۴۲، شماره ۱۲، صفحات ۴۱۶۷-۴۱۷۵
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عنوان انگلیسی Electrically Conductive Sealing Silicone Compositions Filled with Carbon Materials
چکیده انگلیسی مقاله Electrically conductive sealants and coatings have been of great interest in recent years due to advances in electronics and technology. There are not many studies that use siloxanes as matrices. This work aimed to obtain an inexpensive electrically conductive composite using a silicone matrix and carbon fillers: carbon black, graphite, and coal. Introducing a carbon filler led to a significant change in the electrical conductivity of the silicone composite. With an increase in the carbon filler in the composite material from 5 to 30 wt.% there was a natural increase in its electrical conductivity from 10-9 –10–4 up to 8.3×10-6 – 1.11×102 (Ohm×m) -1. This trend is observed for all types of carbon filler. The lower conductivity of graphite and activated carbon is due to the polycrystalline structure and the content of amorphous carbon. The SEM method has established the distribution of particles in the composite matrix with an increase in the filler content, which contributes to a denser packing of aggregates and closer contact between them, due to which conditions are created for the formation of electrically conductive circuits. In this work, the best filler for the electrically conductive sealant was carbon black, at a content of 30% wt. demonstrating an electrical conductivity of 1.11×102 (Ohm×m)–1. However, an increase in the content of carbon black in the matrix hurt the physical and mechanical properties, the nominal tensile strength decreased by 42%, and the elongation at the break by 37%. The resulting composite can be used as an electrically conductive sealing material, but there is a need to improve the physical and mechanical characteristics.
کلیدواژه‌های انگلیسی مقاله Sealing materials,carbon materials,Carbon fillers,Siloxanes,Resistivity,carbon black,Electrical conductivity,Nanocomposites
نویسندگان مقاله Marat I. Tulepov |
Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71, Al-Farabi Avenue, Almaty 050040, KAZAKHSTAN

Zhanat Myshyrova |
Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71, Al-Farabi Avenue, Almaty 050040, KAZAKHSTAN

Rosa Busquets |
School of Life Sciences, Pharmacy and Chemistry, Kingston University, Kingston Upon Thames, KT1 2EE, UNITED KINGDOM

Larissa R. Sassykova |
Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71, Al-Farabi Avenue, Almaty 050040, KAZAKHSTAN

Gulmira Tureshova |
Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71, Al-Farabi Avenue, Almaty 050040, KAZAKHSTAN

Bibigul Rakhimova |
Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71, Al-Farabi Avenue, Almaty 050040, KAZAKHSTAN

Anar Zhapekova |
Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71, Al-Farabi Avenue, Almaty 050040, KAZAKHSTAN

Galiya Spanova |
Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71, Al-Farabi Avenue, Almaty 050040, KAZAKHSTAN

نشانی اینترنتی https://ijcce.ac.ir/article_713992_4f3663a3014ad7b5bae29151a3f79ccf.pdf
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