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JCR 2016
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چهارشنبه 26 آذر 1404
Analytical and Bioanalytical Electrochemistry
، جلد ۱۶، شماره ۱۰، صفحات ۹۴۳-۹۵۶
عنوان فارسی
چکیده فارسی مقاله
کلیدواژههای فارسی مقاله
عنوان انگلیسی
Preparation of Cephalexin Monohydrate Sensors Based on The Synthesis of CeO2 NPs for Potentiometric Determination of Cephalexin Monohydrate in Pure and Commercial Products
چکیده انگلیسی مقاله
Cephalexin monohydrate can be detected using potentiometric sensors made of coated wire electrodes. The Cephalexin monohydrate sensor was made of cerium oxide nanoparticles that were made using green synthesis techniques. At concentrations of 3.0×10
-9
-1.0×10
-2
mol.L
-1
, an excellent response was observed with values of -54.78 and -54.76 mV.decade
-1
, respectively. The detection limits were between 4.0×10
-2
and 9.8×10
-2
mol.L
-1
for CEX-PT-CeO
2
NPs containing a sensor's leaves extract of
Myrtus communis
and CEX-PT-CeO
2
NPs containing a sensor's leaves extract of
Mentha
. For CEX-PT-CeO
2
NPs with
Myrtus communis
sensor leaves extract and CEX-PT-CeO
2
NPs with
Mentha
sensor leaves extract, the PH ranged from 3.5 to 6.5, and the lifetime was 52 days. With concentrations of 8.0×10
-10
-1.0×10
-2
mol.L
-1
, the CEX-PT-CeO
2
NPs sensor displayed a non-Nernstian response close to -35.96 mV.decade
-1
, limit of detection of 4.0×10
-10
mol. L
-1
, with a pH of 3.0-8.0. As a CEX-PT-CeO
2
NPs sensor, a new coated wire electrode was developed in this study. The limit of detection, selectivity, and concentration range of the two sensors were all very high. These sensors were used to find Cephalexin monohydrate in pharmaceutical and pure products.
کلیدواژههای انگلیسی مقاله
Green synthesis,Potentiometric method,Detection limit,XRD Analysis,Coated wire electrode
نویسندگان مقاله
Amina Mohsen Abass |
Department of Chemistry, College of Sciences, Al-Nahrain University, Baghdad, Al-Jaderia, Iraq
Fadam Muteb Abdoon |
Department of Chemistry, College of Science, Tikrit University, Tikrit, Iraq
نشانی اینترنتی
https://www.abechem.com/article_717551_920d1fb4ad02c4c7cdf1f8d109139f82.pdf
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en
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