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جستجوی مقالات
چهارشنبه 26 آذر 1404
Iranian Journal of Chemical Engineering
، جلد ۲۱، شماره ۳، صفحات ۱۴-۳۳
عنوان فارسی
چکیده فارسی مقاله
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عنوان انگلیسی
Experimental Measurement and Thermodynamic Modeling of CO2 Absorption in a Wide Range of Aqueous MDEA Solutions (10-98 wt%)
چکیده انگلیسی مقاله
In this study, the process of capturing CO
2
by using an aqueous MDEA solution under the operating conditions of the concentration range of 10-98 wt% of MDEA, temperature range of 303-323K and atmospheric pressure is investigated. Most researchers have measured the effect of pressure changes on the loading, but in this work, we have investigated the effect of changing the concentration of amine on the loading. We employed the apparatus introduced by Pahlavanzadeh et al. to evaluate the solubility of carbon dioxide in the aqueous solutions of N-methyldiethanolamine (MDEA). The results indicate that the maximum absorption of CO
2
takes place in concentration of between 40-50 wt% of MDEA. Subsequently, the Cubic-Two-State Equation of State (CTS EoS) was improved and used to describe the solubility of CO
2
in aqueous MDEA solutions in a wide range of concentrations and temperatures. This equation, referred to as CTS
DH
, includes three terms relating to the different intermolecular interactions happening in electrolyte solutions. The same EoS was used for vapor and liquid phases. Model parameters were adjusted according to the experimental results of this work and other researches. Using the adjustable parameters from this work, the model successfully approximated CO
2
loading under a wide range of functional conditions. The evaluation of model results with experimental data showed the average absolute percent deviation (AAD%) to be 7.05%, indicating a satisfactory alignment between model predictions and Measured results.
کلیدواژههای انگلیسی مقاله
Vapor-liquid equilibria,CO2 absorption,MDEA,Experimental measurement,Thermodynamic Modeling
نویسندگان مقاله
M. S. Sedighi |
Department of Chemical Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran
H. Pahlavanzadeh |
Process Engineering Department, Faculty of Chemical Engineering, Tarbiat Modares University, Tehran, Iran
M. Arjmand |
Department of Chemical Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran
M. Goharrokhi |
Department of Chemical Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran
نشانی اینترنتی
https://www.ijche.com/article_206316_0359bc1168cafe0945dae95e81cd15ce.pdf
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