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Analytical and Bioanalytical Chemistry Research، جلد ۲، شماره ۲، صفحات ۷۳-۸۴

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عنوان انگلیسی Removal of Dibenzothiophene Using Activated Carbon/γ-Fe2O3 Nano-Composite: Kinetic and Thermodynamic Investigation of the Removal Process
چکیده انگلیسی مقاله In the present study, removal of dibenzothiophene (DBT) from model oil (n-hexane) was investigated using magnetic activated carbon (MAC) nano-composite adsorbent. The synthesized nano-composite was characterized by FT-IR, FE-SEM, BET and VSM techniques. The MAC nano-composite exhibited a nearly superparamagnetic property with a saturation magnetization (Ms) of 29.2 emu g-1, which made it desirable for separation under an external magnetic field. The magnetic adsorbent afforded a maximum adsorption capacity of 38.0 mg DBT g-1 at the optimized conditions (adsorbent dose, 8 g l-1; contact time, 1 h; temperature, 25 °C). Langmuir, Freundlich and Temkin isotherm models were used to fit equilibrium data for MAC nano-composite. Adsorption process could be well described by the Langmuir model. Kinetic studies were carried out and showed the sorption kinetics of DBT was best described by a pseudo-second-order kinetic model. In addition, the MAC nano-composite exhibited good capability of recycling to adsorb DBT in gasoline deep desulfurization.
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نویسندگان مقاله مریم فیاضی |
shahid bahonar university of kerman
سازمان اصلی تایید شده: دانشگاه شهید باهنر (Shahid bahonar university)

محمد علی طاهر | mohammad ali
research institute of environmental sciences

داریوش افضلی |
environment department, research institute of environmental sciences, international center for science, high technology amp;amp; environmental sciences, kerman, iran

علی مصطفوی |
department of chemistry, faculty of sciences, shahid bahonar university, kerman, iran
سازمان اصلی تایید شده: دانشگاه شهید باهنر (Shahid bahonar university)


نشانی اینترنتی http://www.analchemres.org/article_10158_245cc0572200492c0c8e3ebb1cf6008e.pdf
فایل مقاله اشکال در دسترسی به فایل - ./files/site1/rds_journals/378/article-378-332578.pdf
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زبان مقاله منتشر شده en
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