این سایت در حال حاضر پشتیبانی نمی شود و امکان دارد داده های نشریات بروز نباشند
Progress in Color, Colorants and Coatings، جلد ۱۸، شماره ۳، صفحات ۲۶۷-۲۷۸
عنوان فارسی
چکیده فارسی مقاله
کلیدواژه‌های فارسی مقاله
عنوان انگلیسی Deep Fluorescence Solvatochromic Study of Nitrogen Doped Carbon Dots: Polar Sensitive Nanoprobe Application
چکیده انگلیسی مقاله In this research, we synthesized nitrogen-doped carbon dots using three isomers of phenylenediamine (o-PDA, m-PDA, and p-PDA) as nitrogen sources and citric acid as the carbon source. We selected these isomers to study their effect on surface chemistry and optical characteristics. The carbon dots produced contain nitrogen, carboxyl, and hydroxyl groups that interact with the environment and exhibit a change in emission based on the surroundings. Our team conducted an in-depth analysis of the fluorescence emissions exhibited by carbon dots. The study involved examining the behavior of these particles in solvents with varying degrees of polarity, ranging from weakly polar CHCl3 to strongly polar protic water and a binary mixture of H2O-Acetone. The results of the study provide valuable insights that could contribute to advancing our understanding of carbon dots properties. Interestingly, with increasing the water content of organic solvents, the carbon dots changed their fluorescence color from blue to green. We utilized the Lippert-Mataga plot to exhibit a direct correlation between polarity and carbon dots emission wavelength, which demonstrated a positive linear trend as the polarity was increased. The slope for the three isomers was ∆µ=38959, 42115, 2346.5 for O-CD, M-CD and P-CD, respectively. Our results confirm that the polarity of CDs in ground state is less than exited state (μg < μex). This study helps us understand the solvent-dependent behavior of nitrogen-doped carbon dots, particularly their solvent polarity characteristics. We also analyzed the optical properties of M-CD and found a linear response to the polarity and water content of the organic solvent, which suggests the possibility of M-CD as a humidity sensor for detecting water in organic solvents. 
کلیدواژه‌های انگلیسی مقاله Solvatochromic,Nitrogen doped,Carbon dots,Phenylenediamine,Binary solvent,Humidity sensing
نویسندگان مقاله M. Kaviani Darani |
Department of Organic Colorant‏,‏ Institute for Color Science and Technology, P. O. Box: 16765-654, Tehran‎‏,‏ Iran.‏

Sh. Rouhani |
Department of Organic Colorant‏,‏ Institute for Color Science and Technology, P. O. Box: 16765-654, Tehran‎‏,‏ Iran.‏

Z. Ranjbar |
Department of Surface Coatings and Corrosion, Institute for Color Science and Technology, P.O. Box: 16765-654, Tehran, Iran

نشانی اینترنتی https://pccc.icrc.ac.ir/article_82052_c1e8f9c0a4dd31821f0d96a8729b36f6.pdf
فایل مقاله فایلی برای مقاله ذخیره نشده است
کد مقاله (doi)
زبان مقاله منتشر شده en
موضوعات مقاله منتشر شده
نوع مقاله منتشر شده
برگشت به: صفحه اول پایگاه   |   نسخه مرتبط   |   نشریه مرتبط   |   فهرست نشریات