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Iranian Journal of Public Health، جلد ۴۳، شماره ۵، صفحات ۶۴۵-۵۷
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عنوان انگلیسی Coupling of Molecular Imprinted Polymer Nanoparticles by High Performance Liquid Chromatography as an Efficient Technique for Sensitive and Selective Trace Determination of 4-Chloro-2-Methylphenoxy Acetic Acid in Complex Matrices.
چکیده انگلیسی مقاله 4-chloro-2-methylphenoxy acetic acid (MCPA) is one of the most important pesticides which is extensively used to control weeds in arable farmland. Exposure to this compound occurs in general population and persons who occupationally handle it. The aim of this present work was the preparation of MCPA imprinting polymer and its application as a selective sample preparation technique for trace determination of MCPA in biological and environmental samples.In this study, MCPA imprinting polymer was obtained by precipitation polymerization using methacrylic acid (the functional monomer), ethylene glycol dimethacrylate (the cross-linker), 2, 2'-azobisisobutyronitrile (the initiator) and MCPA (the template molecule) in acetonitrile solution. The MIP-NPs were characterized by thermogravimetric analysis and scanning electron microscopy. The optimization process was carried out applying batch method. After optimization of the parameters, affecting the adsorption and desorption of analyte, urine and different water samples were used to determine MCPA.Imprinted MCPA molecules were removed from the polymeric structure using acetic acid in methanol (20:80 v/v %) as the eluting solvent. Both sorption and desorption process occur within 10 min. The maximum sorbent capacity of the molecular imprinted polymer is 87.4 mg g-1. The relative standard deviation and limit of detection for water samples by introduced selective solid phase extraction were 4.8% and 0.9 μg L-1, and these data for urine samples were 4.5% and 1.60 μg L-1, respectively.The developed method was successfully applied to determine MCPA in urine and different water samples.
کلیدواژه‌های انگلیسی مقاله
نویسندگان مقاله فریبرز امیدی | fariborz omidi
1. dept. of occupational health engineering, school of public health, shahroud university of medical sciences , shahroud, iran.


محمد بهبهانی | mohammad behbahani
2. dept. of chemistry, faculty of science, shahid beheshti university, g.c. , tehran, iran.

سازمان اصلی تایید شده: دانشگاه شهید بهشتی (Shahid beheshti university)

سعدی صمدی | saadi samadi
2. dept. of chemistry, faculty of science, shahid beheshti university, g.c. , tehran, iran.

سازمان اصلی تایید شده: دانشگاه شهید بهشتی (Shahid beheshti university)

علیرضا صدیقی | alireza sedighi
3. dept. of occupational health, school of public health, tehran university of medical sciences , tehran, iran.

سازمان اصلی تایید شده: دانشگاه علوم پزشکی تهران (Tehran university of medical sciences)

سید جمال الدین شاه طاهری | seyed jamaleddin shahtaheri
4. dept. of occupational health engineering, school of public health, institute for environmental research, tehran university of medical sciences , tehran, iran.

سازمان اصلی تایید شده: دانشگاه علوم پزشکی تهران (Tehran university of medical sciences)

نشانی اینترنتی http://ijph.tums.ac.ir/index.php/ijph/article/view/4089
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